I noticed this happening to me also sometimes on my new Droid. I am not sure what it is but it usually fixes itself. I do have the Taskiller program and kill my tasks all the time I tried adding Gmail to the ignore list and testing but it didn't help either.
I have my inbox as syncing all, i turned off my sent box from syncing this morning and the mail worked again. Not sure if this was why but it makes me wonder if you make a change to a setting..

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